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Abstract This study presents detailed time-integrated and time-resolved spectral analysis of the Fermi Gamma-ray Burst Monitor observations of the bright GRB 231129C. The results reveal its distinct spectral characteristics, featuring a hard low-energy spectral index (α) and soft high-energy spectral index (β), similar to GRB 090902B, suggesting a possible dominance of thermal emission. Further analysis indicates that 92% of the spectral indices exceed the synchrotron “line of death,” with the hardest index atα∼ +0.44. Simultaneously, 53% of the spectra can be well fitted by the nondissipative photosphere model, supporting a potential origin from a nondissipative photosphere. Additionally, we observe strong correlations between the spectral indexαand peak energyE_pwith flux. For theα−Frelationship, we employF=F₀e^{(3.00±0.10)α}to describe it, whereas theE_p−Frelationship requires a smoothly bending power-law function. Based on the framework proposed by Hascoët et al. and Gao & Zhang, the jet characteristics of this burst were studied, revealing that both methods support the suitability of a pure fireball model for this GRB at small initial jet radii.